5-(PROP-2-YN-1-YL)-5H-DIBENZO[B,F]AZEPINE: ORTHORHOMBIC POLYMORPH

5-(Prop-2-yn-1-yl)-5H-dibenzo[b,f]azepine: orthorhombic polymorph

5-(Prop-2-yn-1-yl)-5H-dibenzo[b,f]azepine: orthorhombic polymorph

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In the title orthorhombic polymorph (space group Iba2), Banjo Strings C17H13N, the dihedral angle between the benzene rings is 55.99 (10)° and the azepine ring adopts a boat conformation.In the crystal, molecules are linked by C—H.π contacts.

The previously-reported polymorph [Yousuf et al.(2012).Acta Cryst.E68, o1101] crystallizes in the monoclinic system (space group Basket P21/c) with two molecules in the asymmetric unit.

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